At 10,982 miles (17,673 km), Madrid to Sydney (Mascot) is beyond the nonstop range of most airliners and is usually flown with a stop. Nonstop on a widebody it would take about 19h 34m.
Sydney (Mascot) is 8 hours ahead of Madrid. You cross 8 time zones heading east. Eastbound trips like this one tend to be harder to adjust to, so plan for a day or two of jet lag.
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